Main characters
Alice
- Portrayed by: Jenna Elfman
- The Alcoholic: Not very, but still.
- Dark and Troubled Past: Alice had a tough childhood and her parents were always fighting and they were neglecting her.
Mary
- Voiced by: Rachel Dratch
"With my help, you're gonna kick life in the A-double-S! That's a swear word. I'll teach you a bunch."
- Advice Backfire: When giving advice to Alice
- Imaginary Friend
- It's All About Me: She seems to be more focused on her and Alice's friendship than Alice dating Ben and being a mother to his kids.
- Jerkass: She probably became more selfish and self-centered after being alone all those years and she hadn't accepted Alice's future.
- Lack of Empathy: She's dismissive to the Cooper children.
- LEGO Body Parts: Revealed in one episode, she can rip her ears off at any time.
- Secondary Character Title: Despite that she's the title character, she serves as the deuteragonist as Alice is the protagonist.
Cooper family
Ben Cooper
- Portrayed by: Stephen Schneider
Andy Cooper
- Portrayed by: Nicholas Coombe
Dora Cooper
- Portrayed by: Matreya Scarrwener
Bunny Cooper
- Portrayed by: Erica Tremblay