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Osawa Eriko
The titular "Boss" of the Special Criminal Countermeasures Unit.
- The Chessmaster: She always finds a way to outsmart the villains.
- Hard-Drinking Party Girl: She's quite a heavy drinker.
- Old Maid: Single, and 40 years old in the first season.
Katagiri Takuma
- Covert Pervert: Revealed in the second season. When a sex club owner mentions swimsuits among other types of costumes used by his employees, Katagiri asks him whether school swimsuits are available.
- The Leader: The most capable of his group when Osawa is not around.
- Shrinking Violet: He is extremely shy around women.
- Sweet Tooth: Enjoys cakes and parfaits.
Yamamura Keisuke
- Attention Deficit... Ooh, Shiny!: Easily distracted by beautiful flowers and butterflies.
- Casanova Wannabe: Believes himself to be more charming than he actually is, and frequents cabaret clubs.
- The Klutz: His forgetting his bag and carrying only its strap around without noticing is a Running Gag.
Kimoto Mami
- Not a Morning Person/Heavy Sleeper: Frequently seen in the office with her head on a pillow.
- Took a Level in Badass: Single-handedly disarms a bomber at the end of Season 2.
Hanagata Ippei
- Butt-Monkey: Tends to get ridiculed by both his superiors and civilians, and get into trouble.
- The Klutz: Tends to mess up the crime scenes in the early episodes.
- Momma's Boy: He really loves his mother.
- Naïve Newcomer: 23 years old, fresh out of the police academy. The top brass looks down on him due to his naive thoughts and childish ambitions like "joining the police force to protect his mother".
Nodate Shinjiro
- Handsome Lech: Always ogles and flirts with the ladies, and frequently organizes goukon (group blind date) parties.
Tadokoro Sachiko
- Big Eater: Frequently seen eating something, especially onigiri.
- Obfuscating Stupidity: Her marksmanship is much better than it looks like.
- Stealth Hi/Bye: Somehow her teammates don't notice her until she speaks up.