She lambasted Ash regularly for his poor training, despite Starmie and Psyduck being just as poor under her handling. Dumb luck is usually relied on when it comes to Psyduck; her Starmie, who is supposed to be her ace, is never seen winning any battles on screen.
She is equally bad at taking her level of criticism back, despite being so keen on criticizing Ash. The first time Ash called her out on this in the latter's case, she threatened him with silence in frustration. Like Ash, this trait mostly toned down as episodes passed, even if she retained a lot more of a similar cockiness than she'd like to admit.
Team Rocket. They get incensed when someone steals from them, even though the heroes were merely reclaiming what the villains stole in the first place.
The samurai from the fourth episode really gets hypocritical. He berates Ash for not finishing what he started... even though he wasn't polite by waiting for Ash to finish catching that darn Weedle. Instead, he rudely and instantly challenges him to a Pokemon battle, leaving the Weedle enough time to escape and warn its Beedrill buddies. And to top it off, he calls Ash a terrible trainer for not rescuing Metapod when a Beedrill took it away even though Ash tries to call it back, but the Beedrill kept out of the way with its agility.
Mewtwo wants to destroy humans because he hates them for cloning him. How does he go about this destruction? By making clones. The dub changes his motivation, as he wants to sever the link between humans and Pokemon simply because he thinks all humans treat Pokemon as tools. And, of course, he is using Pokemon as tools to accomplish this.
Falkner states how he hates the consensus that Flying types would always lose to Electric types due to a type disadvantage and then subsequently patronizes Ash for using Chikorita, for no reason besides her type disadvantage.
Max has a tendency to criticize May and Ash for their flaws as a coordinator & a trainer respectively, but when it was time for Max to battle one time, he knew almost nothing about battling.
Paul can be one:
Paul tells Ash to his face that when a Pokémon loses, it's the trainer's fault for not training it correctly — Paul also blames his own Pokémon, like Chimchar, for their losses.
In the finals of the Tag Team Tournament, he maintains his belief that Chimchar and Ash are weak since Heracross was still briefly standing despite being hit point blank by a Flamethrower, and that it only fainted because Buizel collided with it when hit by Electabuzz's Thunder. While accurate, the exact same thing would apply for Paul and Electabuzz as Buizel was briefly still standing despite being hit point blank by a move it was weak too as well.
Paul is willing to place his own Pokémon on the field when they're type-disadvantaged (he sent the Fire-type Chimchar out to face Roark's Rock-type Pokémon), but criticizes Ash for his own tendency to do the same thing (especially the one time when he criticized Ash for using Grotle in Candice's gym).
Cyrus, the leader of Team Galatic is one. He scolds his underlings for their eagerness to kill Ash and his friends in the finale, after he previously tried to blow up Iron Island in order to do just that.
Cilan’s rival Burgundy is one in spades:
She calls Cilan "arrogant", despite her own overblown ego.
Her vendetta against Cilan is based on Cilan supposedly criticizing her harshly, yet she often criticizes other trainers and their Pokémon harshly.
During the Clubsplosion, she insulted Cilan for losing in the second round, in spite of the fact that she lost in the first round. In fact, Burgundy has not had one single win in the series (except an off-screen win with Chili).
During the Junior Cup, she calls Georgia a "pipsqueak," even though Georgia is actually slightly taller than her.
Goh from the Journeys series has two moments:
He tells Scorbunny that he should expand his horizons when they first meet. Yet, in the preview of Kicking It from Here Into Tomorrow!, he's shown to be dismissive of Scorbunny's desire to become stronger because he thinks that Double Kick/Quick Attack is perfect. Moreover, he doesn't want Scorbunny — the Fire-type — to learn a Fire-Move, yet he caught a Darmanitan just three episodes prior.
In JN135, he swears off his friendship with Ash when the newly-minted WCS Monarch announces he and Pikachu are taking another journey alone—when Goh was going to make a similar announcement himself, having held back out of fear he would destroy his friendship with Ash. Cinderace calls him out hard for this.
In Omega Ruby, he leads the team who believes co-existence between humans and Pokémon is silly and will hinder humanity's progress, while he has two Morality Pets that are Pokémon.
Pokémon Black and White has Ghetsis, who claims N is a freak without a human heart, when it was Ghetsis who was manipulating N the whole time. N is his son. Cheren and Alder do note this, though. N was only trying to do what he felt was right, but Ghetsis is a self-serving monster.
Or when it's just you and your close friends looking. Who kicks a Munna?
In fact, N seems to be the only member of Team Plasma who is not a hypocrite, at least until Pokémon Black 2 and White 2. In that game, he is the leader of a splinter group of Plasma with more noble goals that opposes the current group.
N, however, has his own team of Pokémon despite being against catching them and using them for battles.
N's Pokémon are always local, though, implying that he always releases them back to their homes after facing you. In addition, he admits to the practice, saying that the only way to change the system is to reach the top of it (that is, become League champion, and then, presumably, disband it).
Pokémon X and Y has Lysandre. He hates thieves, liars, and selfish people and wants to eliminate them from the world. Who does he hire? Team Flare; a group that is made up of the very kind of people he claims to hate and he wants to blow up the world and start it over with THESE people. He's either really stupid or this trope. Not to mention that he steals a bunch of pokeballs from the Pokeball Factory. What's worse? No one ever calls him out on it.
